David Cannon (Whirlwind)[]
With sufficient momentum, he can spin up vertical substances.
Jessica Drew (Spider-Woman)[]
Spider-Woman's limbs can adhere to surfaces via electrostatic attraction. Spider-Woman can hold and carry a considerable amount of extra weight while sticking to walls without falling off; it's safe to assume that the weight she can carry is dozens of times her own, and the limits of how long she can do this before fatigue sets in are still unknown.
Peter Parker (Spider-Man)[]
Spider-Man's exposure to the mutated spider venom induced a mutagenic, cerebellum-wide alteration of his engrams resulting in the ability to mentally control the flux of inter-atomic attraction between molecular boundary layers. This overcomes the outer electron shell's normal behavior of mutual repulsion with other outer electron shells and permits the tremendous potential for electron attraction to prevail. The mentally-controlled sub-atomic particle responsible for this has yet to be identified. This ability to affect the attraction between surfaces is so far limited to Spider-Man's body and another object, with an upper limit of several tons per finger. At one point, Spider-Man was able to prevent Anti-Venom from taking his mask off by making it stick to his face.
Rico (Scorpion Boy)[]
Rico is able to walk on the roof at a pretty high speed.
Victor Borkowski (Anole)[]
Similar to Spider-Man, Anole can climb vertically up walls and hang from ceilings from pads on his hands and feet.